Rp0170hd1985sg protection of austenitic stainless steel. Although the deterioration of austenitic stainless steels. Stress corrosion crackingscc is the main corrosion failure mode for 310s stainless steel. Why are austenitic stainless steels more susceptible to. Stress corrosion cracking scc is the main corrosion failure mode for 310s stainless steel. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion. Heat treatments for austenitic stainless steels great. When sulfides are present in caustic solutions the scc has been reported to occur at lower temperatures. Stress corrosion cracking scc is a sudden cracking and failure of a component without deformation.
Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. A general definition of the phenomenon is that scc is the fracture of a material by the simultaneous action of a tensile stress and a corrosive environment. One of the most important forms of stress corrosion that concerns the nuclear industry is chloride stress corrosion. Stress corrosion cracking is the cracking of a susceptible metal under the mixed influence of a tensile stress either residual or applied in a corrosive environment 46. Normally 50 deg c but can occur at lower temperatures around 25 deg c in specific environments, notably swimming pools. Introduction one of the most accepted mechanisms of stress corrosion cracking scc i. Stress corrosion cracking scc is a common issue with many specialty alloys. Carbon steel and ferritic stainless steels, with little to no nickel, do not experience cl scc, nor do high nickel alloys those with ni over 30% are much less prone. Stress corrision cracking is a relatively rare form of corrosion, which requires a specific combination of tensile stress, temperature and corrosive species, often the chloride ion, for it to occur. Stress corrosion cracking scc of austenitic stainless and.
Certain austenitic stainless steels and aluminium alloys crack in the presence of chlorides. Caustic stress corrosion cracking, also referred to as caustic embrittlement, is a form of degradation that is caused when a component operates in a caustic environment. Carbon and lowalloy steels scc can occur in other materials stainless steel ss is susceptible to scc when exposed to chloride solutions stress is required could be only residual. Stress corrosion cracking scc of austenitic stainless steel in boiling 42% mgcl 2 solution under compressive stress was investigated. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides.
C for 500 h under drops of synthetic seawater det, drop evaporation test. The combination of tensile stress and a specific corrosive environment can crack stainless steels. Einziger, marine atmosphere stress corrosion cracking 20. Note that tsujikawa found that the critical temperature could range from 420c to 0c by. Stress corrosion cracking scc of austenitic 304 stainless steel in chloride environment is a common problem in industries. The micrograph on the left x300 illustrates scc in a 316 stainless steel chemical processing piping system. Chloride stress corrosion cracking in austenitic stainless.
Grades with high resistance to chlorideinduced stress corrosion cracking scc duplex stainless steels, austenitic stainless steels with a high nickel content 25%. Austenitic grades, however, are susceptible to chloride stress corrosion cracking scc and are not recommended for service that combines tensile stress and the presence of chlorides, even at moderate temperatures. Stress corrosion cracking the international institute of. It is one of the most prevalent afflictions in the industry and one of many environmental cracking mechanisms that typically occur in carbon steel equipment, but it can also afflict low alloy and austenitic stainless steel. Stress corrosion cracking of austenitic stainless steel under. Stress corrosion cracking scc of uns s31603 austenitic stainless steel ass, uns s32205 duplex stainless steel dss and uns s32750 super duplex stainless steel sdss was investigated. The stress corrosion cracking scc and hydrogen embrittlement he behaviors for types 304, 310, and 316 austenitic stainless steels were investigated in boiling saturated magnesium chloride solutions using a constant load method under different conditions including test temperature, applied stress, and sensitization. The following sandvik grades have very good or excellent resistance to chlorideinduced stress corrosion cracking. Chloride stress corrosion cracking in austenitic stainless steel is characterized by the multibranched lightning bolt transgranular crack pattern. Chloride stress corrosion cracking in austenitic stainless steel.
Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. Ferritic steels are also resistant to cracking but may corrode. Controlling stress corrosion cracking scc in order for scc to occur, we require a susceptible material, an environment that will cause cracking of that material and a high enough stress or stress intensity factor. Pitting and stress corrosion cracking behavior of austenitic stainless steel weldments containing retained ferrite. This chapter focuses on stress corrosion cracking scc of austenitic stainless steels in high temperature light water reactor lwr environments, and emphasizes common grades of wrought austenitic stainless steel over cast, ferritic or martensitic stainless steels. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. Jun 10, 2016 310s is an austenitic stainless steel for high temperature applications, having strong resistance of oxidation, hydrogen embrittlement and corrosion. Experimental data from published literature on stress corrosion cracking scc of austenitic stainless steels ss as influenced by temperature and stress in concentrated chloride solutions were analyzed using the chemicalmechanical correlation model. Rp0170hd1985sg protection of austenitic stainless steel from polythionic acid stress corrosion cracking during shutdown of refinery equipmenthd1985 available for download methods to protect austenitic stainless steel from polythionic acid stress corrosion cracking scc found to occur during downtimes and contiguous shutdown and startup.
Stress corrosion cracking of an austenitic stainless steel in. Pdf stress corrosion cracking of austenitic stainless. Although no stainless steel grade is totally immune. The part is stressed by an applied load or by residual stress. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media. In addition to stress, oxygen is a critical ingredient to enable scc nitrogen aggravates the process source.
Highnickel alloys abrass aluminum alloys titanium alloys magnesium alloys zirconium alloys environment hot nitrate, hydroxide, and. Stress corrosion cracking scc of austenitic stainless steel weld metal. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of. Chloride stress corrosion cracking in austenitic stainless steel chloride stress corrosion cracking clscc is one of the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Stress corrosion cracking of austenitic stainless steel. Caustic stress corrosion cracking, also referred to as caustic embrittlement, is a form of degradation that is caused when a component operates in a caustic environment it is one of the most prevalent afflictions in the industry and one of many environmental cracking mechanisms that typically occur in carbon steel equipment, but it can also afflict low alloy and austenitic stainless steel.
Therefore, the scc concerns for spent fuel storage canisters identified in a november 2004 presentation by nuclear and. Past researched about scc of 310s primarily focus on the corrosion mechanism and influence of temperature and corrosive media, but few studies. Highnickel alloys abrass aluminum alloys titanium alloys magnesium alloys zirconium alloys environment hot nitrate, hydroxide, and carbonatebicarbonate solutions. Rr902 chloride stress corrosion cracking in austenitic.
Past researched about scc of 310s primarily focus on the corrosion mechanism and influence of temperature and corrosive media, but few studies concern the. Stress corrosion cracking scc of austenitic stainless. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Figure 1 shows the cracking that occurred on a 6mo super austenitic stainless steel n08367 exposed to 0.
It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. This mode of attack is termed stress corrosion cracking scc. Stress corrosion cracking scc of austenitic stainless steels in high. Laboratory tests were conducted to investigate the stress corrosion cracking scc of 304l stainless steel used to construct the containment vessels for the storage of plutoniumbearing materials. Stress corrosion cracking of duplex stainless steel scc stress corrosion cracking is a form of corrosion which occurs with a particular combination of factors. Effects of marine environments on stress corrosion cracking. Effects of laser peening on stress corrosion cracking scc of ansi 304 austenitic stainless steel author links open overlay panel j. Stress corrosion cracking international institute of. Addition of nitrite to the chloride solution, which is reported to have inhibitive influence on corrosion of stainless.
The environment is aggressive high chloride level, temperature above 50 c, presence of h 2 s. With regard to the safe temperature for carbon steel, the reader should look at the curve in figure 1. This article describes the susceptibility of 316l stainless steel to stress corrosion cracking scc in a nitritecontaining chloride solution. When austenitic stainless steels with sufficient carbon. Effects of temperature and pressure on stress corrosion.
This limits the usefulness of austenitic stainless steel for. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. It is difficult to control the temperature, while changing pipe material or eliminating residual stresses associated with welding and forming the pipework is costly and. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. The risk of stress corrosion cracking scc is minimized by stress relief.
Both of type 304 and type 316 stainless steels showed quite similar. Effects of laser peening on stress corrosion cracking scc. Effect of ph and chloride contents on stress corrosion. The resistance of austenitic stainless steels to scc is related to the nickel content of the steel. Chloride stress corrosion cracking ssina specialty steel. The nickel content in austenitic stainless steels helps to reduce the rate of corrosion, particularly in acid environments.
Oct 18, 2016 cold worked austenitic stainless steels will contain some strain induced martensite, which, as well as making the steel partially ferromagnetic, can also reduce the corrosion resistance. Stress corrosion cracking scc of stainless steel canister in marine environment for longterm dry storage of spent nuclear fuel, extended storage collaboration program meeting, december 2011, adams accession no ml1350299. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of. Chloride stress corrosion cracking cl scc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. Specimens with surface residual compressive stress, ubend specimens, and notched compressive specimens of modified wol type were used. There are, consequently, a number of approaches that we can use to prevent scc, or at least to give an acceptable lifetime. Stainless steels are more resistant to general corrosion compared with carbon steel. Caustic stress corrosion cracking inspectioneering. Scc can occur typically in hot water tanks or swimming pools. Chloride stress corrosion cracking clscc is one the most common reasons. Effects of stress and temperature on stress corrosion. Stress corrosion cracking scc sandvik materials technology. A highly stressed cold worked structure may also have lower general corrosion resistance than a fully softened austenitic structure. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances.
Effects of marine environments on stress corrosion. Stress corrosion cracking scc of duplex stainless steel. Even here, stress corrosion cracking scc may occur due to contamination, either of the product in the pipe or vessel or externally from sea water, particularly where the liquid is able to concentrate in crevices. Investigation of stress corrosion cracking of austenitic. Austenitic stainless steels suffer from scc in chlorides, caustic, and polythionic acid. Stress corrosion cracking of an austenitic stainless steel.
On the stress corrosion cracking and hydrogen embrittlement. Austenitic stainless steels chloride induced stress corrosion cracking cscc chumpes petroleum 16 mar 18 10. The micrograph below x300 illustrates scc in a 316 stainless steel chemical processing piping system. Duplex stainless steels, austenitic stainless steels with a high nickel content 25 %.
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